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ASPECT CONSULTING <br />64 FINAL PROJECT NO. AS190583A-08  MAY 21, 2025 <br />independent Phase 2 ESA. Two sample foc values were excluded from the calculation of <br />the site-wide average foc: the 0.0564 foc measurement in sample GF-B-3-11-12.5 was <br />determined to be a statistical outlier (high), and sample GF-B-9-7.5-9 (foc = 0.0048) <br />contained an elevated diesel-range TPH concentration (6,400 mg/kg). In addition, two soil <br />samples that were subsequently removed during interim action excavations—thus are not <br />representative of current Site soil conditions—were excluded from the calculation. <br />Although large quantities of aggregate were imported to the Site for use as excavation <br />backfill during the interim actions, these materials are not contaminated and were, <br />therefore, excluded from the determination of Site-specific soil foc in accordance with <br />MTCA (WAC 173-340-747(5)(b)(i)). Table 5-5 presents the Site-specific soil foc data used <br />in the calculation, and the excluded values. Because Ecology’s CLARC database does not <br />define a soil organic carbon-water partition coefficient (Koc) or Henry’s Law constant for <br />cPAH mixtures, the values for those parameters assigned for total cPAHs in the <br />calculations was the average of CLARC’s listed values for the seven individual cPAH <br />compounds. <br />As agreed to with Ecology, the soil-to-groundwater pathway is not considered for <br />constituents that have not been positively identified in groundwater at concentrations <br />exceeding groundwater PCLs. Constituents for which the soil-to-groundwater pathway is <br />considered in the derivation of soil PCLs are presented in Tables 5-3 and 5-4 (“Y” in the <br />column labeled “Groundwater Exceedances Confirmed Empirically for Analyte?”). <br />The soil concentrations predicted by this MTCA-default methodology are intentionally <br />conservative for the purposes of data screening in the RI. Because this default <br />methodology is a conservative predictive model rather than an empirical measurement, it <br />is possible that soil concentrations greater than these PCLs are not actually leaching <br />contaminants to groundwater at concentrations exceeding groundwater PCLs. MTCA <br />provides a range of options to evaluate Site-specific soil concentrations protective of <br />groundwater, including the use of soil leaching tests and empirical groundwater quality <br />data, as outlined in WAC 173-340-747. Empirical groundwater data indicating that <br />groundwater meets PCLs is the strongest and most reliable evidence that soil <br />concentrations in that vicinity (upgradient) are protective of groundwater. The <br />demonstration of whether soil concentrations are protective of groundwater is evaluated <br />based on all RI data (Section 6.3), which factors into soil cleanup levels established for the <br />Upland Area. <br />5.3.2.3 Risk-Based Soil PCLs for Petroleum Mixtures <br />Site-specific, risk-based Method C soil PCLs can be calculated for TPH mixtures, <br />addressing all exposure pathways (including soil leaching to groundwater) using volatile <br />petroleum hydrocarbon (VPH) and/or extractable petroleum hydrocarbon (EPH) data to <br />quantify concentrations of aromatic and aliphatic hydrocarbons in specific carbon ranges <br />for the specific petroleum product, in accordance with MTCA (WAC 173-340- <br />745(5)(b)(iii)(B)(III)). This approach is implemented for specific areas of industrial land <br />use in the Upland Area where residual petroleum remains in place following interim <br />actions as presented in Section 6.5, and the MTCA calculations are detailed in Appendix <br />F. Because of the multiple petroleum types beneath the warehouse building, MTCA