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ASPECT CONSULTING <br />PROJECT NO. AS190583A-08  MAY 21, 2025 FINAL 73 <br /> <br />The pH effect of groundwater seasonally coming into and out of contact with CM is <br />illustrated clearly by data collected from Log Pond well LP-MW-1. Well LP-MW-1 <br />historically had the highest pH readings measured on the Site (up to 13.0 in November <br />2013) due to the facts that (1) its well screen was shallow enough that it intercepted the <br />thick layer of CM in that area, and (2) the Log Pond fill has low enough permeability that <br />precipitation does not infiltrate there nearly as readily as the dredge fill outside of the Log <br />Pond (refer to Section 2.4.4.2.3). Consequently, when the seasonal rains began, the <br />groundwater level within the Log Pond footprint “mounded up” because infiltration is so <br />slow. The mounded groundwater submerged CM within the well’s screened interval, <br />which created very high pH groundwater in the shallow depth interval screened by <br />LP-MW-1. Figure 6-P10 illustrates the relationship of groundwater level and pH measured <br />at well LP-MW-1 over time. The bottom of the CM at that well is depicted for comparison <br />with groundwater elevations on the figure. <br />Between February and August 2016, the groundwater level at well LP-MW-1 dropped <br />approximately 3.5 feet, to below the bottom of the CM at that location, with a <br />corresponding groundwater pH drop from 11.2 to 8.6 in that well. By March 2017, the <br />groundwater level at LP-MW-1 rose nearly 4 feet relative to August 2016 and was 0.4 feet <br />higher than that measured in February 2016. In the peak dry-season conditions of <br />September 2017, the water level was again below the bottom of the CM and the <br />groundwater pH was 8.15—the same phenomenon observed in the dry season of 2016. <br />During groundwater pH monitoring conducted for the CM removal project, the pH <br />readings in LP-MW-1 ranged from 7.0 to 7.5 between August 31 and September 22, 2020. <br />During this period, on September 3, the water level was measured to be 7.0 feet below the <br />well’s top of casing and thus below the base of the CM. Between September 24 and 26, <br />2020, approximately 1.6 inches of rain fell in Everett. By September 28, the pH in <br />LP-MW-1 had risen to 9.7; the water level was not measured that day. On September 29, <br />when a pH of 10.5 was measured, the water level had risen to 3.3 feet below top of casing. <br />Comparing the September 3 and September 29 readings, the water level rose about <br />3.7 feet, submerging the base of the CM, and the pH increased about 3.3 standard units in <br />response (Figure 6-P10). These data, in combination with low pH measured in the deeper <br />wells installed in 2017 within the Log Pond (LP-MW-3 through LP-MW-7), indicate that <br />the elevated groundwater pH was limited to a shallow depth interval beneath the CM <br />layer. <br />In areas where the CM did not contact groundwater, relatively higher groundwater pH <br />occurred where the thickness of the CM layer was greatest and where the water table was <br />shallowest. The depth of the water table generally increases from east to west across the <br />Upland Area. Apart from the localized CM-filled subsurface structures, the thickest <br />occurrences of CM—greater than 5 feet—were generally present within the center of the <br />Log Pond and within the Tissue Mill areas. <br />6.3.1 Time Trends for Groundwater pH <br />While there is seasonality in the groundwater pH, the data collected between 2013 and <br />2021 also demonstrate that, prior to CM removal, the elevated pH was gradually declining