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ASPECT CONSULTING <br />108 FINAL PROJECT NO. AS190583A-08  MAY 21, 2025 <br />6.5.4.2.4 Mercury <br />Prior to the second IA, concentrations of mercury up to 3.8 mg/kg were present in soil on <br />the east side of the chip reclaim conveyor foundation (Aspect, 2019b). As discussed <br />above, the second IA removed more than 400 tons of contaminated soil from the Log Pond <br />Chip Conveyor Area. Four of 13 compliance soil samples collected at the limits of the <br />second IA Log Pond Chip Conveyor area contained mercury above but less than two times <br />the soil PCL of 0.1, with concentrations ranging from 0.11 mg/kg to 0.17 mg/kg <br />(Table 6-9). <br />Similar to copper, of the 17 locations where mercury is reported in soil at concentrations <br />above the PCL, five contain exceedances only in the sawdust layer. However, mercury is <br />not present at concentrations above the groundwater PCL in groundwater samples <br />collected from deep wells LP-MW-03, LP-MW-05, LP-MW-06, or LP-MW -07, <br />empirically demonstrating that mercury is not leaching to groundwater from the sawdust <br />layer at concentrations of concern (Table 6-10). <br />Dissolved mercury exceeds the groundwater PCL of 0.025 µg/L in Log Pond wells <br />LP-MW-01 and LP-MW-02, with concentrations ranging from 0.033 µg/L to 0.248 µg/L <br />and positive correlations between elevated mercury concentrations and elevated <br />groundwater pH (Table 6-10). Dissolved mercury concentrations in intertidal porewater <br />samples from the PW-05 location were less than the PCL (Figure 6-C8; Table 6-22). <br />6.5.4.2.5 Nickel <br />The only soil exceedance for nickel in Unit C is the 48.5 mg/kg detection at the <br />HW-MW-01 location, relative to the 48 mg/kg PCL based on natural background <br />concentrations. A statistical evaluation of all nickel soil data from Unit C indicates a <br />95 percent UCL of 27 mg/kg, which is below the soil PCL of 48 mg/kg, with 1.1 percent <br />of samples (1/93) exceeding the PCL, and no samples with concentrations greater than two <br />times the PCL. Nickel soil concentrations within Unit C are in compliance with the PCL. <br />Groundwater nickel exceedances occur in the same wells as the other groundwater metals <br />exceedances occur including shoreline wells MW-06 and LP-MW-02 (Figure 6-C9). <br />Nickel exceedances were inconsistently detected at all Log Pond Area wells and were only <br />detected above the PCL during a single sampling event in the two shoreline wells <br />(Table 6-10). Dissolved nickel concentrations in intertidal porewater samples from the <br />PW-5 location were less than the PCL (Figure 6-C9; Table 6-22). <br />Shoreline groundwater in Unit C is generally not as aerobic (less than 1 mg/L on average) <br />as measured at multiple shoreline wells in Units A and B (Table 6-11). The low D.O. is a <br />further indication of the lack of tidal exchange with shoreline groundwater zone within the <br />Log Pond (discussed in Section 2.4.4). These data are consistent with the hypothesis for <br />higher nickel concentrations present in aerobic shoreline groundwater in Units A and B: <br />that phenomenon is not occurring in the largely anaerobic shoreline groundwater within <br />the Log Pond Area of Unit C. <br />6.5.4.3 PCBs <br />Concentrations of total PCB Aroclors exceed the saturated soil PCL at six locations within <br />the Log Pond (Figure 6-C12). At five of these locations, the PCB exceedances are reported