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ASPECT CONSULTING <br />PROJECT NO. AS190583A-08  MAY 21, 2025 FINAL 111 <br /> <br />limits for cPAHs at shoreline wells at LP-MW-02 and MW-06 were elevated during initial <br />sampling events, but subsequent sampling events had reporting limits below the PCL. <br />The deep sawdust layer contains TPH-D+O, PAHs, and PCBs at concentrations exceeding <br />the soil PCLs. However, groundwater samples collected from deep wells screened across <br />the sawdust layer do not contain TPH-D+O or PAHs exceeding the groundwater PCLs, <br />indicating that these contaminants are not leaching from the organic-rich sawdust at levels <br />that result in exceedances of the PCLs. PCB congeners were detected above the <br />groundwater PCL in four Log Pond Area wells, including both shallow and deep wells, <br />but are not present in shoreline wells above the PCL. <br />The highest concentrations of NH3 in Upland Area groundwater were detected at inland <br />well LP-MW-01 within the Log Pond Area, which was a large storage area for wood chips <br />for decades during mill operations; this well also had the highest groundwater pH <br />measured on Site37. Subsurface wood waste also exists in the Log Pond fill from past <br />filling activities. Considerably lower-level NH3 exceedances were detected at the Log <br />Pond shoreline wells LP-MW-02 and MW-06, but they are still three times the PCL based <br />on surface water exposure. <br />Within the intertidal zone adjacent to Unit C, NH3 and H2S were each detected at <br />concentrations exceeding PCLs in one of two porewater samples. No NH3 or H2S <br />exceedances were detected in samples of East Waterway surface water collected along the <br />toe of the Log Pond Area’s rip rap slope, demonstrating the rapid attenuation of these <br />compounds within oxygenated water. <br />The existing analytical data for soil and groundwater within the Log Pond Area of Unit C <br />provide sufficient information for the development and evaluation of cleanup action <br />alternatives in accordance with MTCA. <br />6.5.5 Unit D <br />The explorations and IA areas within Unit D, including IA compliance soil sample <br />locations, are depicted on Figure 6-D1. For current conditions following the IA, the <br />constituents detected in one or more samples of Unit D media at concentrations exceeding <br />their respective PCLs are as follows: <br /> TPH-D+O in soil <br /> Total cPAHs (TEQ) in soil and groundwater <br /> Total xylenes in soil <br /> Arsenic, copper, mercury, and nickel in soil and groundwater <br /> Lead and zinc in soil <br /> Dissolved sulfide in groundwater and intertidal porewater/seeps <br /> <br />37 NH3 concentrations correlate directly with pH (refer to Appendix H).